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51.
The representer method was used by [Ngodock, H.E., Jacobs, G.A., Chen, M., 2006. The representer method, the ensemble Kalman filter and the ensemble Kalman smoother: a comparison study using a nonlinear reduced gravity ocean model. Ocean Modelling 12, 378–400] in a comparison study with the ensemble Kalman filter and smoother involving a 1.5 nonlinear reduced gravity idealized ocean model simulating the Loop Current (LC) and the Loop Current eddies (LCE) in the Gulf of Mexico. It was reported that the representer method was more accurate than its ensemble counterparts, yet it had difficulties fitting the data in the last month of the 4-month assimilation window when the data density was significantly decreased. The authors attributed this failure to increased advective nonlinearities in the presence of an eddy shedding causing the tangent linear model (TLM) to become inaccurate. In a separate study [Ngodock, H.E., Smith, S.R., Jacobs, G.A., 2007. Cycling the representer algorithm for variational data assimilation with the Lorenz attractor. Monthly Weather Review 135 (2), 373–386] applied the cycling representer algorithm to the Lorenz attractor and demonstrated that the cycling solution was able to accurately fit the data within each cycle and beyond the range of accuracy of the TLM, once adjustments were made in the early cycles, thus overcoming the difficulties of the non-cycling solution. The cycling algorithm is used here in assimilation experiments with the nonlinear reduced gravity model. It is shown that the cycling solution overcomes the difficulties encountered by the non-cycling solution due to a limited time range of accuracy of the TLM. Thus, for variational assimilation applications where the TLM accuracy is limited in time, the cycling representer becomes a very powerful and attractive alternative, given that its computational cost is significantly lower than that of the non-cycling algorithm.  相似文献   
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53.
Many modern seafloor tectonic environments are host to hydrothermal systems and associated polymetallic sulfide deposits. Metal transport and precipitation are controlled by magmatic processes such as pre-eruptive degassing and the hydrothermal cycle. The original availability of Pb and other ore metals in a given setting is dependent on concentrations in the original magmatic source or additional enrichment processes. We have examined the Pb budget of melt inclusions from nine modern seafloor settings representing back-arcs, mid-ocean ridges and seamounts. Melt inclusions provide information on the characteristics of parental magmas, including insights into metal budgets. Trace element data in melt inclusions hosted in plagioclase, olivine and pyroxene were obtained by laser-ablation inductively-coupled mass-spectrometry.Results from back-arcs emphasize the impact of slab-subduction and dehydration processes on the chemical characteristics of generated magmas. Volatile- and fluid-mobile element-rich melt inclusions at Manus basin and Okinawa trough reflect a robust contribution of elements from the subducting slab as evidenced by relatively low Ce/Pb ratios. At Bransfield strait, on the other hand, melt inclusions are volatile poor, and fluid-mobile element ratios are similar to mid-ocean ridge values indicating little or no contribution from the slab. High Cu concentrations at Manus basin and Okinawa trough can be explained by fluxing of ferric iron from the subducting slab benefiting the production of sulfate over sulfide.Metal budgets for seamounts located on and nearby the axis of mid-ocean ridge segments appear to be independent of any input of mantle plume material. Results from the southern Explorer ridge (strong lower mantle influence, transitional- and enriched-MORBs), Pito and Axial seamounts (moderate lower mantle influence, transitional-MORBs) and a Foundation near-ridge seamount (little to no mantle influence, normal-MORB) show that, despite similar tectonic environments and varying contributions of mantle plume material, Cu, Zn and Pb values do not vary significantly between the enriched and non-enriched magma components of a given setting.  相似文献   
54.
Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary (macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ15N) and carbon (δ13C). The δ15N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source loading. There is also evidence of a west to east gradient of heavy to light values of δ15N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ15N values in macroalgae there reflected preferential uptake of 14N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of dissolved C species may control the observed δ13C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ15N (13.2 ± 0.54‰ SD) and δ13C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ15N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources.  相似文献   
55.
Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.  相似文献   
56.
A comprehensive study of meteorological, hydrological, limnological and sedimentological conditions in the watersheds of density-stratified (meromictic) lakes around Taconite Inlet, Northern Ellesmere Island, N.W.T., Canada was carried out from 1990–1992. Lakes C1 and C2 contain seawater trapped by isostatic uplift as the former embayments became isolated from the sea. These lakes, and Lake C3, contain varved sediments which provide an annually resolvable paleoclimatic record. By studing the major systems influencing sedimentation in one of these lakes (Lake C2) a better understanding of the climatic controls on varve formation, and hence on the paleoclimatic signal in the varved sediment record, was obtained. The varves of Lake C2 provide a proxy record of summer temperature for the region.This is the first in a series of papers published in this issue on the Taconite Inlet Lakes Project. These papers were collected by Dr R. S. Bradley.  相似文献   
57.
A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m3/s, and those of the overflows between 35 and 110 m3/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.  相似文献   
58.
Temperature fluctuations in interstellar dust grains caused by absorption of ultraviolet photons are discussed. Temperature probability distributions are presented for various assumptions about the grain specific heat and far infrared emissivity. Grains smaller than or about 0.01 may suffer large temperature fluctuations and would spend most of their time at very low temperatures. The equilibrium temperature is not a good measure for most average temperatures of such grains. It is shown that, although small grains spend only a small fraction of their time at the higher temperatures, the emitted far infrared spectrum is significantly shifted towards shorter wavelengths than predicted for grains assumed to be at the equilibrium temperature.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.  相似文献   
59.
Radiation damage and luminescence, caused by magnetospheric charged particles, have been suggested by several authors as mechanisms for explaining some of the peculiar spectral/albedo features of Io. We have pursued this possibility by measuring the uv-visual spectral reflectance and luminescent efficiency of several proposed Io surface constituents during 2 to 10-keV proton irradiation at room temperature and at low temperature (120 < T < 140°K). The spectral reflectance of NaCl and KCl during proton irradiation exhibits the well-known F-center absorption bands at 4580 and 5560 Å. Na2SO4 shows a generalized darkening which increases toward longer wavelengths. NaNO3 shows a spectral reflectance change indicative of the partial alteration of NaNo3 to NaNo2. NaNO2 shows no change. The luminescent efficiencies of NaCl and KCl are ~10?4 at 300°K and increase by one-half order of magnitude at ~130°K. The efficiencies of K2CO3, Na2CO3, Na2SO4, and NaNO3 are 10?4, 10?4, 10?5 and 10?6, respectively, at 300°K and they all decrease by one-half order of magnitude at ~130°K. These results indicate that magnetospheric proton irradiation of Io could cause spectral features in its observed ultraviolet and visible reflection spectrum if salts such as those studied here are present on its surface. However, because the magnitude of these spectral effects is dependent on competing factors such as surface temperature, incident particle energy flux, solar bleaching effects, and trace element abundance, we are unable at this time to make a quantitative estimate of the strength of these spectral effects on Io. The luminescent efficiencies of pure samples that we have studied in the laboratory suggest that charged-particle induced luminescence from Io's surface might be observable by a spacecraft such as Voyager when viewing Io's dark side.  相似文献   
60.
Observations of the vertical profile of hydrogen fluoride (HF) vapor in the stratosphere and of the vertical column amounts of HF above certain altitudes were made using a variety of spectroscopic instruments in the 1982 and 1983 Balloon Intercomparison Campaigns. Both emission instruments working in the far infrared spectral region and absorption instruments using solar occultation in the 2.5m region were employed. No systematic differences were seen in results from the two spectral regions. A mean profile from 20–45 km is presented, with uncertainties ranging from 20% to 50%. Total columns measured from ground and from 12 km are consistent with the profile if the mixing ratio for HF is small in the tropophere and low stratosphere.  相似文献   
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